Journal
METALLURGICAL AND MATERIALS TRANSACTIONS B-PROCESS METALLURGY AND MATERIALS PROCESSING SCIENCE
Volume 51, Issue 6, Pages 2993-3006Publisher
SPRINGER
DOI: 10.1007/s11663-020-01976-9
Keywords
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Funding
- National Research Council of Science & Technology (NST) Grant by the Korea government (MSIT) [CRC-15-06-KIGAM]
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A novel electrolytic process that uses a liquid-metal cathode was investigated to produce high-purity magnesium (Mg) metal using magnesium oxide (MgO). Electrolysis of MgO in a magnesium fluoride (MgF2)-lithium fluoride (LiF) molten salt was carried out with applied voltages of 2.5 V to 3.0 V at 1053 K to 1083 K using tin (Sn), silver (Ag), or copper (Cu) as the cathode and graphite or platinum (Pt) as the anode. After electrolysis, Mg alloys with Mg2Sn, AgMg, and Cu2Mg phases were produced with current efficiencies of 77.2 to 83.8 pct when the concentration of Mg in the Mg alloys was 11.9 to 12.9 mass pct. For the production of high-purity Mg metal directly from the Mg alloys, vacuum distillation was performed. When vacuum distillation was conducted at 1200 K to 1300 K, the concentration of Mg in the Mg alloys feed decreased from 30.2 to 34.1 mass pct to 0.32 to 1.75 mass pct, and Mg metal with a purity of 99.975 to 99.999 pct was obtained. Therefore, this study demonstrates that the production of high-purity Mg metal through an efficient and environmentally sound method using the electrolysis of MgO is feasible.
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