4.7 Review

Multicomponent Reactions in Polymer Chemistry Utilizing Heavier Main Group Elements

Journal

MACROMOLECULAR RAPID COMMUNICATIONS
Volume 42, Issue 6, Pages -

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/marc.202000495

Keywords

main group elements; multicomponent polymerizations; multicomponent reactions; postpolymerization modification

Funding

  1. Australian Research Council (ARC)
  2. ARC Laureate Fellowship
  3. Queensland University of Technology (QUT)

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This concise overview provides insights into the use of heavier main group elements in multicomponent reactions and polymer chemistry, focusing on the properties of Group 13, Group 14, Group 15, and Group 16 elements. It briefly explores elements that participate in the reaction mechanism and remain in the macromolecular structure. State-of-the-art work in developing these reactions is highlighted, aiming to inspire other polymer chemists to explore different parts of the periodic table.
Herein, a concise overview of the use of heavier main group elements in multicomponent reactions and their use in polymer chemistry is provided. Incorporating heavier elements into macromolecular structures via multicomponent reactions allows for the rapid development of materials with unique properties that are not readily achieved using carbon, nitrogen, and/or oxygen. Elements in Group 13, Group 14, Group 15, and Group 16 are specifically covered examining both the familiar and unfamiliar properties of these elements and how they are used in multicomponent chemistry. Furthermore, elements that both take part in the reaction mechanism and remain in the macromolecular structure upon completion are only briefly explored. Some of the state-of-the-art work going into developing these heavier element multicomponent reactions are highlighted and it is hoped to inspire other polymer chemists to explore other parts of the periodic table.

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