Journal
MACROMOLECULAR RAPID COMMUNICATIONS
Volume 42, Issue 6, Pages -Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/marc.202000459
Keywords
functional polymers; Hantzsch reaction; multicomponent reactions
Categories
Funding
- National Nature Science Foundation of China [21971141, 21534006]
- Tsinghua-UNSW Initiative Scientific Research Program [2020Z02NSW]
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The Hantzsch reaction is a powerful tool for synthesizing 1,4-dihydropyridine derivatives, and has recently been introduced into polymer chemistry for developing polymers with new functions. These polymers with 1,4-DHP structures have potential applications in various fields. The future development of the Hantzsch reaction is promising for exploring new functional polymers.
The Hantzcsh reaction is a robust four-component reaction for the efficient generation of 1,4-dihydropyridine (1,4-DHP) derivatives. Recently, this reaction has been introduced into polymer chemistry in order to develop polymers having 1,4-DHP structures in the main and/or side chains. The 1,4-DHP groups confer new properties/functions to the polymers. This mini-review summarizes the recent studies on the development of new functional polymers by using the Hantzsch reaction. Several synthetic approaches, including polycondensation, post-polymerization modification (PPM), monomer to polymer strategy, and one-pot strategy are introduced; different applications (protein conjugation, formaldehyde detection, drug carrier, and anti-bacterial adhesion) of the resulting polymers are emphasized. Meanwhile, the future development of the Hantzsch reaction in exploring new functional polymers is also discussed.
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