Journal
MACROMOLECULAR RAPID COMMUNICATIONS
Volume 42, Issue 3, Pages -Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/marc.202000378
Keywords
biodegradable polymers; organocatalysis; polycarbonates; polymers; ROP
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Funding
- European Commission [SUSPOL-EJD 642671]
- Fonds National de la Recherche Scientifique (FRS-FNRS)
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The synthesis of well-defined propargyl-functional aliphatic polycarbonates is achieved using commercially available or readily made, shelf-stable organocatalysts, resulting in homopolymers with low dispersities and end-group fidelity, and demonstrating the versatility of the system through the synthesis of telechelic copolymers and block copolymers with molar mass up to 40 kDa.
The synthesis of well-defined propargyl-functional aliphatic polycarbonates is achieved via the organocatalytic ring-opening polymerization of prop-2-yn-1-yl 2-oxo-1,3,6-dioxazocane-6-carboxylate (P-8NC) using a wide variety of commercially available or readily made, shelf-stable organocatalysts. The resulting homopolymers show low dispersities and end-group fidelity, with the versatility of the system being demonstrated by the synthesis of telechelic copolymers and block copolymers with molar mass up to 40 kDa.
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