4.8 Review

Insights into the Structure and Dynamics of Metal-Organic Frameworks via Transmission Electron Microscopy

Journal

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 142, Issue 41, Pages 17224-17235

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/jacs.0c08773

Keywords

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Funding

  1. National Science Foundation's MRSEC program [NSF DMR-1720139]
  2. Army Research Office [W911NF-181-0359, W911NF-191-0340]
  3. Air Force Research Laboratory [FA8650-15-2-5518]
  4. Ryan Fellowship
  5. Northwestern University International Institute for Nanotechnology
  6. NSF Graduate Research Fellowship [DGE-1842165]
  7. Human Frontier Science Program [LT000869/2018-C]
  8. Research Corporation for Science Advancement (RCSA) through the Cottrell Fellowship Initiative - National Science Foundation [CHE-2039044]
  9. Department of Energy, Office of Basic Energy Sciences, Division of Materials Science and Engineering [DE-FG02-08ER46519]

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Metal-organic frameworks (MOFs) are hybrid materials composed of metal ions and organic linkers featuring high porosity, crystallinity, and chemical tunability at multiple length scales. A recent advancement in transmission electron microscopy (TEM) and its direct application to MOF structure-property relationships have changed how we consider rational MOF design and development. Herein, we provide a perspective on TEM studies of MOFs and highlight the utilization of state-of-the-art TEM technologies to explore dynamic MOF processes and host-guest interactions. Additionally, we provide thoughts on what the future holds for TEM in the study of MOFs.

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