Journal
CORROSION SCIENCE
Volume 102, Issue -, Pages 233-250Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.corsci.2015.10.012
Keywords
Steel; Copper; Polarization; EIS; Modelling studies
Funding
- BP
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A potential model for the prediction of metal corrosion inhibition using relevant pure and mixed surfactants in salt solution has been developed and validated. This model is based on the combination of Langmuir adsorption (LA) and a newly-developed critical micelle concentration (cmc) prediction model for various pure and mixed surfactants. The collected data from benzalkonium chloride (BAC) surfactants was used for model illustration and derivation. The effects of surfactant concentration, adsorption, aggregation, and solution temperature on steel corrosion inhibition were investigated. The adsorption mechanism is discussed based on temperature, concentration, potential of zero charge, and density functional theory (DFT) calculation. (C) 2015 Elsevier Ltd. All rights reserved.
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