Journal
CORROSION SCIENCE
Volume 106, Issue -, Pages 157-171Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.corsci.2016.02.001
Keywords
Stainless steel; TEM; XPS; Oxidation; Reactor conditions
Funding
- International Cooperative Project - Science and Technology Commission of Shanghai Municipality [13520721200]
- Ph.D. Programs Foundation of the Ministry of Education of China [20123108110021]
- Shanghai Pujiang Project [12PJ1403600]
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Oxide films formed on 316L stainless steel, 9Cr-26Ni-1.5Mo, and 9Cr-26Ni-1.5Mo-5Si in de-aerated high temperature water have been characterized. High reactivity of Si and high solubility of silicon oxides in high temperature water contribute to Si depletion in the outer oxide layer, Si enrichment in the inner oxide layer near the metal/oxide interface, and the outer layer of large and continuously packed oxides with cavities. A higher Cr content in the alloys favors the formation of a thinner inner oxide layer. Si in the model alloy affects the distribution of nickel oxide near the metal/oxide interface. (C) 2016 Elsevier Ltd. All rights reserved.
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