Journal
JOURNAL OF PHYSICAL CHEMISTRY B
Volume 124, Issue 44, Pages 9884-9897Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.jpcb.0c05547
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Funding
- Hungarian NKFIH Foundation [119732, 134596]
- EFOP project Complex Development of Research Capacities and Services at the Eszterha'zy Ka'roly University [EFOP-3.6.1-16-2016-00001]
- Czech Science Foundation [1816577S]
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The surface tension of all aqueous alkali halide solutions is higher than that of pure water. According to the Gibbs adsorption equation, this indicates a net depletion of these ions in the interfacial region. However, simulations and experiments show that large, soft ions, such as I-, can accumulate at the liquid/vapor interface. The presence of a loose hydration shell is usually considered to be the reason for this behavior. In this work, we perform computer simulations to characterize the liquid-vapor interface of aqueous alkali chloride and sodium halide solutions systematically, considering all ions from Li+ to Cs+ and from F- to I-. Using computational methods for the removal of surface fluctuations, we analyze the structure of the interface at a dramatically enhanced resolution, showing that the positive excess originates in the very first molecular layer and that the next 3-4 layers account for the net negative excess. With the help of a fictitious show that it is not possible to rationalize the surface affinity of ions in solutions in system with charge-inverted ion pairs, we also terms of the properties of anions and cations separately. Moreover, the surface excess is generally dominated by the smaller of the two ions.
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