Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 85, Issue 20, Pages 13069-13079Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.0c01757
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Funding
- Welch Foundation [E-0044]
- NIGMS [R01GM077635]
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N-Aminopyridinium ylide-directing group is employed for copper-promoted chalcogenation of sp(2) C-H bonds with aryl and alkyl disulfides as well as diphenyl diselenide. Reactions proceed in hexafluoroisopropanol (HFIP) solvent at elevated temperatures and are promoted by copper(II) acetate.
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