Journal
COORDINATION CHEMISTRY REVIEWS
Volume 306, Issue -, Pages 235-269Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.ccr.2015.07.007
Keywords
Metallasiloxanes; Coordination interactions and; supramolecular aggregation; Catalysis; Structural rearrangements
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Funding
- RFBR [14-03-00713]
- Russian Federation [MD-3589.2014.3]
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The traditional and recent synthetic approaches to polyhedral metallasiloxanes (PHMSs) of different types are reviewed to demonstrate that each strategy yields a PHMS with a specific structure, which is typical of the particular synthetic approach selected. The factors governing the structures and transformations of PHMSs are analyzed, including examples of the formation of supramolecular aggregations of PHMSs. (C) 2015 Elsevier B.V. All rights reserved.
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