Journal
COORDINATION CHEMISTRY REVIEWS
Volume 319, Issue -, Pages 180-195Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.ccr.2016.03.016
Keywords
Imaging reagent; Metallopolymer; Sensor; Stimuli-responsive materials
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Funding
- National Natural Science Foundation of China [61274018, 61136003, 21501098]
- Scientific and Technological Innovation Teams of Colleges and Universities in Jiangsu Province [TJ215006]
- Priority Academic Program Development of Jiangsu Higher Education Institutions
- Synergetic Innovation Center for Organic Electronics and Information Displays
- Natural Science Foundation of Jiangsu Province of China [BK20130038, BK20150833, BM2012010]
- Nanjing University of Posts and Telecommunications [NY213097, NY214083]
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Stimuli-responsive metallopolymers have been drawing great research interest in the design and development of novel sensory materials. Smart metallopolymers combining advantages of both metal complexes and polymers exhibit good solubility and processibility, and show changes in conformation, conductivity, color, and luminescence in response to external stimuli. This review article summarizes the recent development of metallopolymers that are responsive to environmental physical parameters such as temperature, electricity, and light and chemical analytes such as pH values, ions and gas molecules. The applications of these stimuli-responsive metallopolymers as biological sensors and imaging reagents in biological environments have also been discussed. (C) 2016 Published by Elsevier B.V.
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