Journal
JOURNAL OF MOLECULAR STRUCTURE
Volume 1227, Issue -, Pages -Publisher
ELSEVIER
DOI: 10.1016/j.molstruc.2020.129369
Keywords
Phosphorus heterocyles; Dft; Negative fukui-function; Activation energy; Dual reactivity descriptor
Categories
Funding
- Faculty of Natural Sciences of the University of Atacama [Incubal0/2018]
Ask authors/readers for more resources
This work presents a study on the theoretical determination of reactivity and structures of complex phosphorus heterocycles, explaining surprising rearrangement reactions and reactivities of a phosphorus bicycle using the Fukui function and dual reactivity descriptors. The structure of the main starting compound with a very short non-bonding C-C-distance is described as a fast equilibrium in solid state rather than as non-classical ylid, and the negative values of Fukui functions found in some structures are discussed.
In this work we present a study on the theoretical determination of reactivity and structures of complex phosphorus heterocycles. Applying the Fukui function and dual reactivity descriptors surprising rearrangement reactions and reactivities of a phosphorus bicycle are explained and, also the hitherto not completely understood structure of the main starting compound with a very short non-bonding C-C-distance is described as a fast equilibrium in solid state rather than as non-classical ylid. Aspects on negative values of Fukui functions found in some structures are discussed. (C) 2020 Published by Elsevier B.V.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available