4.7 Article

Ferromagnetic and antiferromagnetic liquid crystal suspensions: Experiment and theory

Journal

JOURNAL OF MOLECULAR LIQUIDS
Volume 321, Issue -, Pages -

Publisher

ELSEVIER
DOI: 10.1016/j.molliq.2020.114467

Keywords

Liquid crystal; Ferronematic; Goethite nanoparticles; Magnetic and electric Freedericksz transitions; Magnetic properties

Funding

  1. Slovak Academy of Sciences [VEGA 2/0016/17]
  2. Slovak Research and Development Agency [APVV-0150453]
  3. COST action [CA15119 Nanouptake]
  4. Russian Foundation for Basic Research [19-02-00231]
  5. Ministry of Science and Higher Education of the Russian Federation [FSNF-2020-0008]
  6. National Academy of Sciences of Ukraine [0116U008318]
  7. MODEX - Operational Programme Integrated Infrastructure (OPII) - ERDF [ITMS2014+:313011T548]

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This paper presents complete theoretical and experimental studies on electrically and magnetically induced orientational transitions in suspensions of goethite nanorods in a nematic liquid crystal. Different types of samples with varied magnetic properties are prepared and observed. The magnetically induced transitions exhibit distinct orientational behaviors in the samples, with the compensated ferronematic requiring a higher magnetic field for the Freedericksz transition compared to pure nematic, and the magnetized ferronematic showing measurable response to magnetic fields even below the Freedericksz threshold.
In this paper, the complete theoretical and experimental studies of electrically and magnetically induced orientational transitions in suspensions of goethite nanorods in a nematic liquid crystal 4-( trans-4-n-hexylcydohexyl)-isothiocyanato-benzene (6CHBT), known as ferronematics are presented. Two types of samples with different magnetic properties are prepared and observed. A compensated ferronematic with zero initial magnetization is obtained after cooling of the sample from isotropic to nematic phase in the absence of a magnetic field. A magnetized ferronematic with nonzero initial magnetization is prepared during application of magnetic field. The magnetically induced transitions demonstrated two different types of orientational behavior of the samples. The Freedericksz transition in the compensated ferronematic occurred in higher magnetic field in comparison with pure nematic while the magnetized ferronematic shown well measurable response in capacitance to the applied magnetic field, even much below the Freedericksz threshold in usual 6CHBT. Full theoretical descriptions of such behaviours of compensated and magnetized ferronematic samples are presented and all observed dependencies of the cells capacitance on magnetic field are numerically calculated. A comparative analysis shows very well qualitative and quantitative agreement between theoretical results and experimental data. Due to this, the material parameters of the investigated ferronematic system with goethite nanoparticles are estimated. (C) 2020 Elsevier B.V. All rights reserved.

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