Polymer Based ZnO-SiO2Nanocomposite Flexible Sheets as High Dielectric Materials

Flexible dielectric polymer nanocomposites (NCs) with high dielectric permittivity and low loss factor have numerous applications in light emitting and storage devices. In this research work, polymer based NCs in the form of flexible sheets containing 5% ZnO and 15, 20% SiO(2)nano-fillers, are synthesized by using co-precipitation method. X-ray diffraction analysis reveals the development of various diffraction planes related to ZnO and SiO(2)phases confirms the synthesis of polycrystalline PB-ZnO-SiO2NCs flexible sheets corresponding to various compositions. Morphology and compositional analysis show the uniform distribution of nanoparticles in polymer matrix with estimated elemental contents in each composition. Dielectric measurements demonstrate a sharp increase in dielectric permittivity with relatively low dissipation factor in synthesized compositions having ZnO and SiO(2)nano-fillers. The static value of dielectric constant at 100 Hz is found to be 10.79 for sample having 20% SiO(2)nano-fillers that is 3.4 times greater than pure PVA and it shows relatively low value of dissipation factor. The observed AC conductivity of synthesized NCs flexible sheets having 5% ZnO, 20% SiO(2)nano-fillers is 2.15 x 10(-5) S/m that is 3.3 times greater than pure PVA at 1 x 10(6) Hz. Complex impedance spectroscopy further confirms, these materials as promising candidates for better capacitive performance.

Automated summary

This research successfully synthesized flexible sheet-like dielectric polymer nanocomposites containing 5% ZnO and 15, 20% SiO2 nano-fillers, demonstrating high dielectric permittivity and low dissipation factor. The synthesized compositions showed uniform distribution of nanoparticles in the polymer matrix, with significant increase in dielectric constant and relatively low dissipation factor. The AC conductivity of the synthesized flexible sheets was found to be promising for better capacitive performance compared to pure PVA.