4.7 Article

Impact of low temperature plasma annealing for flexible, transparent and conductive ITO/PEDOT:PSS composite electrode

Journal

JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY
Volume 93, Issue -, Pages 423-429

Publisher

ELSEVIER SCIENCE INC
DOI: 10.1016/j.jiec.2020.10.021

Keywords

ITO; PEDOT:PSS; Nano composite; Plasma annealing; Flexible transparent conducting oxides; Thin film heater

Funding

  1. Technology Innovation Program (or Industrial Strategic Technology Development Program) [20006511]
  2. Ministry of Trade, Industry & Energy (MOTIE, Korea)
  3. National Research Foundation of Korea [4199990514093] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)

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This study successfully developed a highly transparent and low resistance ITO/PEDOT:PSS nano composite thin film using low temperature plasma annealing, making it a cost-effective flexible transparent electrode for energy conversion devices.
We report on the development of a cost effective, highly transparent flexible conductive electrode for energy conversion devices using the ITO/PEDOT:PSS nanocomposite. The ITO/PEDOT:PSS nano composite thin film was deposited via bar coating, then its characteristics were examined. In particular, we study any changes in its transparency and resistance. The thin film transparent ITO/PEDOT:PSS was annealed using a low temperature annealing technique called plasma annealing. The purpose of low temperature plasma annealing is to help excite the electrons from their bonding states in the valence band into the antibonding states of the conduction band where a second order phase transition occurs. This study investigates the influence of O-2 plasma annealing on the resistance of the nano composite thin films. The included PEDOT:PSS supports the flexibility of the ITO, as pristine ITO is brittle. High optical transmittance of 93.73% at 550 nm and a reduction in the sheet resistance were achieved using this plasma annealing from 1105 Omega/square to 535 Omega/square on the ITO/PEDOT:PSS nano composite making them excellent candidates to develop as cost effective flexible transparent electrodes that can be used as thin film heaters. (C) 2020 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved.

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