Journal
JOURNAL OF HAZARDOUS MATERIALS
Volume 396, Issue -, Pages -Publisher
ELSEVIER
DOI: 10.1016/j.jhazmat.2020.122741
Keywords
Metal-Organic Coordination Networks; Trihalomethanes; Magnetic Solid-Phase Extraction; DFT Calculation; Interaction Mechanism
Categories
Funding
- Environmental Protection Scientific Research Project of Jiangsu Province [2016056]
- National Key R&D Program of China [2016YFB0302800]
- National Natural Science Foundation of China [21777089]
- Shandong Province Taishan Scholar Program [ts20190948]
- Ji Nan science&Technology Bureau Program [2019GXRC032]
- Qing Lan Project
- Priority Academic Program Development of Jiangsu Higher Education Institutions
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Trihalomethanes (THMs) are the primary toxic and carcinogenic byproducts during disinfection of drinking water. THMs have been frequently detected in water body and posed a huge threat to human health. Thus, analyzing the trace levels of THMs in an accurate and rapid method for water quality monitoring is important. In this paper, silver-based organic coordination networks (Ag-OCN) were fabricated with different diameters under mild pH condition. After modification with magnet, Fe3O4@ Ag-OCN as extractant was applied to the magnetic solid-phase extraction of THMs from water samples. Gas chromatography-tandem mass spectrometry was used for sample quantification and detection. The magnetic extractant displayed good linearity in the range of 0.03-10 ug/L, low limits of detection (1.41-10.13 ng/L), and good reproducibility (relative standard deviations < 6.31%). Moreover, density-functional theory (DFT) calculation was also applied to investigate the possible interaction mechanism. Combining the experimental data with theoretical calculation, results showed that Fe3O4@ Ag-OCN was a potential magnetic material for the enrichment and extraction of formed THMs at trace levels from water samples.
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