Journal
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
Volume 873, Issue -, Pages -Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jelechem.2020.114377
Keywords
Asymmetric supercapacitors; Hierarchical architecture; Metal-organic frameworks; Layered double hydroxides; Electrodeposition
Categories
Funding
- National Key R&D Program of China [2017YFB0309100]
- Key Laboratory of Eco-textiles, Ministry of Education - Fundamental Research Funds for the Central Universities [JUSRP51907A]
- National First-class Discipline Program of Light Industry Technology and Engineering (LITE2018-21)
- Natural Science Foundation of Jiangsu Province [BK20180628]
- Postgraduate Research & Practice Innovation Program of Jiangsu Province [KYCX18_1821]
- National Natural Science Foundation of China [51803078]
- 111 Project [B17021]
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Hierarchical architecture hybrid materials with excellent synergistic effect have been paid close attention for their potential applications in energy storage devices. Herein, we reported an electrode of CoNi layered double hydroxides (LDH) nanosheets electrodeposited on Co3O4 nanoneedles derived from 2D Co-based metal-organic frameworks (Co-MOFs) combined with flexible carbon cloth (CoNi LDH@Co3O4@CC) for asymmetric supercapacitors (ASCs). The Co3O4 nanoneedles served not only as a good pseudocapacitive material but also as an excellent porous skeleton for electrodepositing CoNi LDH nanosheets. The combination of hierarchical core-branch architecture and heterogeneous structure endowed the CoNi LDH@Co3O4@CC electrode with superior electrochemical performance with high specific capacitance (1021.7 F g(-1) at 10 A g(-1)) and good rate capability. Furthermore, the ASC composed of the CoNi LDH@Co3O4@CC as a cathode and N-doped porous carbon nanosheets grown on the carbon cloth (NC@ CC) as an anode achieved a superior energy density of 33.4 W h kg(-1) at a power density of 1600 W kg(-1) and a long cycle life (93.46% after 10,000 cycles at 4 A g(-1)). As a result, this work demonstrated an efficient method for rational design and preparation of the hierarchical core-branch architecture hybrid electrodes for supercapacitors. (C) 2020 Elsevier B.V. All rights reserved.
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