4.7 Article

Fabrication of SiGe/Ge nanostructures by three-dimensional Ge condensation of sputtered SiGe on SiO2/Si substrate

Journal

JOURNAL OF ALLOYS AND COMPOUNDS
Volume 858, Issue -, Pages -

Publisher

ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2020.157653

Keywords

Three-dimensional Ge condensation; Heterojunction; Nanostructure; Schottky barrier height

Funding

  1. National Key R&D Program of China [2018YFB2200103]
  2. National Natural Science Foundation of China [61474094, 61176092]
  3. University of Delaware

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By controlling the width of sputtered Si/SiGe structures and constructing nanowires of different widths before 3D Ge condensation, a SiGe/Ge heterostructure nanowire was successfully fabricated. Inter-diffusion of Si and Ge atoms resulted in a region with gradually varied Ge content, offering a new approach for the fabrication of scalable and low-cost SiGe or Ge nano-devices.
In this work, three-dimensional (3D) Ge condensation of sputtered Si/SiGe nanostructures on SiO2/Si substrate was investigated. Through varying the width of sputtered Si/SiGe structures from 50 tm to 400 nm, the Ge content of fabricated SiGe structures can be modulated from 0.49 to 1.0 after 3D Ge condensation. By further constructing a width modified nanowire (NW) with adjacent widths of 800 nm and 400 nm before 3D Ge condensation, a Si0.33Ge0.67/Ge heterostructure NW was fabricated after 3D Ge condensation. Due to inter-diffusion of Si and Ge atoms, a similar to 2-mu m-long region with gradually varied Ge content from similar to 0.67 to 1.0 is formed between Si0.33Ge0.67 and Ge. The low Schottky barrier height (0.29 eV) of Ge NW/metal contact and good conductivity of the Ge NW suggest that the 3D Ge condensation technique is very promising for fabrication of scalable and low-cost SiGe or Ge nano-electronic/photonic devices. (C) 2020 Elsevier B.V. All rights reserved.

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