Journal
ISRAEL JOURNAL OF CHEMISTRY
Volume 61, Issue 5-6, Pages 298-301Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ijch.202000069
Keywords
cross-electrophile coupling; reductive coupling; rhodium; palladium; formate
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Funding
- Robert A. Welch Foundation [F-0038]
- NIH-NIGMS [RO1-GM069445]
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Two catalytic systems are introduced for the formate-mediated cross-electrophile reductive coupling of aryl iodides with 6-bromopyridines, utilizing homogeneous rhodium or heterogeneous palladium catalysts. The products of reductive biaryl cross-coupling can be obtained in moderate yield with excellent levels of chemoselectivity.
Two catalytic systems for the formate-mediated cross-electrophile reductive coupling of aryl iodides with 6-bromopyridines are described. Using homogenous rhodium or heterogeneous palladium catalysts, the products of reductive biaryl cross-coupling could be formed in moderate yield with excellent levels of chemoselectivity.
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