Journal
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
Volume 45, Issue 43, Pages 23056-23068Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.ijhydene.2020.06.076
Keywords
Formic Acid dehydrogenation; Hydrogen economy; Palladium; Gold; bimetallic catalyst
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Funding
- Spanish Ministerio de Economia y Competitividad (MINECO) - FEDER funds from the European Union [ENE2013-47880-C3-2-R, ENE2017-82451-C3-3-R]
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A series of monometallic and bimetallic palladium gold catalyst were prepared and studied for the formic acid dehydrogenation reaction. Different Pd/Au compositions were employed (PdxAu100-x, where x = 25; 50 and 75) and their impact on alloy structure, particle size and dispersion was evaluated. Active phase composition and reaction parameters such as temperature, formic acid concentration or formate/formic acid ratio were adjusted to obtain active and selective catalyst for hydrogen production. An important particle size effect was observed and related to Pd/Au composition for all bimetallic catalysts. (C) 2020 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
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