Journal
INORGANIC CHEMISTRY COMMUNICATIONS
Volume 119, Issue -, Pages -Publisher
ELSEVIER
DOI: 10.1016/j.inoche.2020.108121
Keywords
Coordination unsaturated; Open metal sites; Cu(II) coordination polymer; Electrochemical reversibility; Photocatalytic degradation
Categories
Funding
- National Natural Science Foundation of China [21801230]
- Natural Science Foundation of Shanxi Province [201801D0221084]
- Scientific and Technological Innovation Programs of Higher Education Institutions in Shanxi [2019L0510]
- Young Academic Leader Supported Program of North University of China [QX201904]
- Opening Foundation of Key Laboratory of Laser & Infrared System (Shandong University), Ministry of Education [2020-LISKFJJ-002]
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A coordination unsaturated copper (II) coordination polymer, [Cu(tptc)(0.5)(bpy)(H2O)](n) (1), was constructed from the mixed ligands of p-terphenyl-2,2 '',5 '',5'''-tetracarboxylate acid (H(4)tptc) and 1,3-bis(imidazol-1 yl-methyl)benzene (bimb) under hydrothermal condition. Structural analysis revealed that CP 1 is a 2D 4-connected {3(2).6(2).7(2)} kgm polymeric sheet, which can be further expanded into 3D supramolecular through hydrogen bonds. The coordination unsaturated central Cu(II) ions endow the CP 1 open metal sites, displaying good electrochemical reversibility as well as high efficiency in photocatalytic degradation of methylene blue (MB) under UV irradiation.
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