Journal
INORGANIC CHEMISTRY
Volume 59, Issue 18, Pages 13078-13090Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.0c00638
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- CNPq
- Coordenacan de Aperfeicoamento de Pessoal de Nivel Superior - Brasil (CAPES) [001]
- CAPES-PRINT [88887.310569/2018-00, 88887.310560/2018-00]
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The new luminescent carbonyl compounds [Mn(Oxa-H)(CO)(3)Br] (1) and [Mn(Oxa-NMe2)(CO)(3)Br] (2) were synthesized and fully characterized. Complexes 1 and 2 showed CO release under blue light (lambda(453)). Spectroscopic techniques and TD-DFT and SOC-TD-DFT calculations indicated that 1 and 2 release the Oxa-H and Oxa-NMe2 coligands in addition to the carbonyl ligands, increasing the luminescence during photo-induction.
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