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Renewable cellulosic nanocomposites for food packaging to avoid fossil fuel plastic pollution: a review

Journal

ENVIRONMENTAL CHEMISTRY LETTERS
Volume 19, Issue 1, Pages 613-641

Publisher

SPRINGER HEIDELBERG
DOI: 10.1007/s10311-020-01090-x

Keywords

Biopolymers; Lignocellulosic biomass; Cellulose nanoparticles; Cellulosic nanocomposites; Food packaging; Sustainable packaging

Funding

  1. EPSRC Project Advancing Creative Circular Economies for Plastics via Technological-Social Transitions (ACCEPT Transitions) [EP/S025545/1]
  2. Bryden Centre Project - The European Union's INTERREG VA Programme [VA5048]
  3. EPSRC [EP/S025545/1] Funding Source: UKRI

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This article reviews the extraction of cellulose nanoparticles from lignocellulosic biomass and the preparation of cellulosic nanocomposites for food packaging. Cellulosic nanocomposites exhibit exceptional properties attributed to the nanoscale structure of cellulose, such as mechanical, biodegradation, optical, and barrier properties. The addition of cellulose nanoparticles improves the mechanical and barrier properties of the composites, with even a small percentage significantly impacting the performance.
The extensive use of petroleum-based synthetic and non-biodegradable materials for packaging applications has caused severe environmental damage. The rising demand for sustainable packaging materials has encouraged scientists to explore abundant unconventional materials. For instance, cellulose, extracted from lignocellulosic biomass, has gained attention owing to its ecological and biodegradable nature. This article reviews the extraction of cellulose nanoparticles from conventional and non-conventional lignocellulosic biomass, and the preparation of cellulosic nanocomposites for food packaging. Cellulosic nanocomposites exhibit exceptional mechanical, biodegradation, optical and barrier properties, which are attributed to the nanoscale structure and the high specific surface area, of 533 m(2) g(-1), of cellulose. The mechanical properties of composites improve with the content of cellulose nanoparticles, yet an excessive amount induces agglomeration and, in turn, poor mechanical properties. Addition of cellulose nanoparticles increases tensile properties by about 42%. Barrier properties of the composites are reinforced by cellulose nanoparticles; for instance, the water vapor permeability decreased by 28% in the presence of 5 wt% cellulose nanoparticles. Moreover, 1 wt% addition of filler decreased the oxygen transmission rate by 21%. We also discuss the eco-design process, designing principles and challenges.

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