4.6 Article

Geometric Optimisation of Quantum Thermodynamic Processes

Journal

ENTROPY
Volume 22, Issue 10, Pages -

Publisher

MDPI
DOI: 10.3390/e22101076

Keywords

quantum thermodynamics; finite-time thermodynamics; thermodynamic length; heat engines; cooling

Funding

  1. la Caixa Foundation [100010434, LCF/BQ/DI19/11730023]
  2. Swiss National Science Foundation [PZ00P2-186067]
  3. EPSRC
  4. European Union [713729]
  5. Spanish MINECO [QIBEQI FIS2016-80773-P, SEV-2015-0522]
  6. Fundacio Cellex
  7. Generalitat de Catalunya [SGR 1381]
  8. Generalitat de Catalunya (CERCA Programme)

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Differential geometry offers a powerful framework for optimising and characterising finite-time thermodynamic processes, both classical and quantum. Here, we start by a pedagogical introduction to the notion of thermodynamic length. We review and connect different frameworks where it emerges in the quantum regime: adiabatically driven closed systems, time-dependent Lindblad master equations, and discrete processes. A geometric lower bound on entropy production in finite-time is then presented, which represents a quantum generalisation of the original classical bound. Following this, we review and develop some general principles for the optimisation of thermodynamic processes in the linear-response regime. These include constant speed of control variation according to the thermodynamic metric, absence of quantum coherence, and optimality of small cycles around the point of maximal ratio between heat capacity and relaxation time for Carnot engines.

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