Journal
ECOTOXICOLOGY AND ENVIRONMENTAL SAFETY
Volume 200, Issue -, Pages -Publisher
ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.ecoenv.2020.110771
Keywords
Starch; Polyacrylamide; AgNPs; Hot spot; Substrate; Organic pollutants
Categories
Funding
- Coordenacao de Aperfeicoamento de Pessoal de Nivel Superior - Brasil (CAPES) [001]
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Herein is presented a simple and sensible method to determine organic pollutants in water, based on the utilization of silver nanoparticles (AgNPs) loaded in Polyacrylamide (PAAm)/starch hybrid hydrogels combined with surface-enhanced Raman scattering (SERS) spectroscopy. The materials were characterized by swelling degree studies, UV-Visible spectroscopy (UV-Vis), X-ray diffraction (XRD) and scanning electron microscopy (SEM). PAAm/starch hydrogels showed variable swelling capacity, according to the synthetic molar composition. The most promising results were attributed to lower concentrations of starch and crosslink agent (N,N'-methylenebisacrylamide - MBA). Spectroscopic analysis confirmed the formation of AgNPs, by noticing the peak at around 420 nm, due to its surface plasmon resonance (SPR) effect. The results showed that AgNPs were stabilized by hydrogels networks. The average size of the AgNPs was smaller than 100 nm and the size and quantity of nanoparticles were influenced by the molar composition of the hydrogel matrix. The SERS substrate based on the AgNPs-PAAm/starch exhibited reproducibility, stability, and limit of detection (LOD) of phenol in water of 1 x 10(-8) M. The average mass of AgNPs-PAAm/starch hydrogels used for each detection analysis was around 10 mg. The spectra with enhanced intensities were possible due to a large number of hot spots generated on the AgNPs-PAAm/starch hydrogel substrate, which leads to potential use for organic pollutant detection. In addition, there is also the possibility of reusing the hydrogel matrix substrate in other analyzes.
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