Journal
COORDINATION CHEMISTRY REVIEWS
Volume 421, Issue -, Pages -Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.ccr.2020.213442
Keywords
Metal-organic framework; Silica material; Porous material; Composite; Adsorption; Catalysis
Categories
Funding
- Fundamental Research Funds for the Central Universities [2020YQHH01]
- National Natural Science Foundation of China [21101062]
- Science and Technology Department of Hubei Province [2014CFB600]
- Foundation of State Key Laboratory of Structural Chemistry [20190003, 20180023]
- Foundation of Hubei Provincial Key Laboratory of Green Materials for Light Industry
- Collaborative Innovation Center of Green Lightweight Materials and Processing, Hubei University of Technology [201907B04, 201907A09, 4032401]
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The fabrication of novel porous materials remains of great interest because of their intriguing architectures, various properties, and promising applications. As typical porous materials with high crystallinity, metal-organic frameworks (MOFs) have attracted continuous attention to the scientific community. However, poor stability and monotonous pore structures hinder their practical and/or advanced applications. To address these concerns, many researchers have devoted themselves to the topics of hierarchical structures and composites by the combination of different components. The present review focuses on the recent advances in MOF-silica composites, where the silica materials can be porous or nonporous. It first provides the fundamentals of porous materials, including zeolites, mesoporous silica, and MOFs, and then shifts to the fabrication of MOF-silica composites. In the following sections, the emphasis of the discussion is placed on the applications of MOF-silica composites, such as adsorption, catalysis, drug release, extraction, magnetism, and sensing. Furthermore, the applications of MOF-silica composites-derived carbon materials are also reviewed and discussed in detail. Finally, it summarizes the achievements of MOF-silica composites and gives an outlook on future research. (C) 2020 Elsevier B.V. All rights reserved.
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