4.5 Article

Crystallographic and shape orientations of magnetite micro-inclusions in plagioclase

Journal

CONTRIBUTIONS TO MINERALOGY AND PETROLOGY
Volume 175, Issue 10, Pages -

Publisher

SPRINGER
DOI: 10.1007/s00410-020-01735-8

Keywords

Plagioclase; Magnetite inclusions; Shape orientation relationships; Crystallographic orientation relationships; Crystal structures; Oxygen layers

Funding

  1. Austrian Science Fund (FWF)

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Plagioclase hosted, oriented magnetite micro-inclusions are a frequently observed phenomenon in magmatic and metamorphic rocks. Understanding the orientation relationships between these inclusions and the plagioclase host is highly relevant for interpreting paleomagnetic measurements. The systematics of the shape and crystallographic orientation relationships between needle- and lath-shaped magnetite micro-inclusions and their plagioclase host from oceanic gabbro were investigated using optical microscopy including universal stage measurements, scanning electron microscopy, and crystal orientation analysis by electron backscatter diffraction. The magnetite inclusions show preferred shape orientations following six well-defined directions and with specific crystallographic orientation relationships to the plagioclase host. These relationships are rationalized based on angular and dimensional similarities between the crystal structures of magnetite and plagioclase, which favor the parallel alignment of oxygen layers with similar lattice spacing in both phases. The parallel alignment of oxygen layers in plagioclase and magnetite can be traced back to the oriented nucleation of magnetite, which occurs by the accommodation of FeO(6)octahedra in six-membered rings of SiO(4)and AlO(4)tetrahedra of the plagioclase structure. The orientation systematics of the magnetite micro-inclusions is related to four orientation variants for placing the FeO(6)octahedra into the plagioclase structure.

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