Effects of silica fume on physicochemical properties and piezoresistivity of intelligent carbon black-cementitious composites

Carbon black (CB) filled cementitious composites as cement-based sensors with intrinsic piezoresistivity have the potential applications for structural health monitoring (SHM). Effect of silica fume (SF) replacement ratio on the physicochemical, mechanical and piezoresistive properties, and microstructure of CB-cementitious composite were experimentally investigated in this study. The results show that 5% or 10% replacement ratio of SF can improve the water impermeability, setting time and electrical conductivity, but decrease the fresh flowability. Cementitious composite with 10% SF exhibiteds excellent compressive and flexural strengths. Moreover, cement hydration in the acceleration stage decreased with the increase of SF content in the early stage, but the phase analysis after 28 days curing demonstrates that with the addition of SF, there are more hydrated products and less ettringite. In addition, the microstructures of cementitious composites without SF present more porous structures and CB agglomerations. In contrast, the amount of micropores or voids was significantly reduced by the addition of SF due to the physical filling effect and less CB agglomerations. In terms of piezoresistivity, SF can obviously improve the fractional changes of resistivity (FCR) under cyclic compression. With 10% SF, CB-cementitious composites as cement-based sensors exhibited excellent FCR and electrical stability, which will promote their development and application in the SHM for smart infrastructures. (C) 2020 Elsevier Ltd. All rights reserved.