Journal
CHINESE CHEMICAL LETTERS
Volume 31, Issue 12, Pages 3213-3215Publisher
ELSEVIER SCIENCE INC
DOI: 10.1016/j.cclet.2020.08.025
Keywords
Chalcogenide; Cluster; In situ; Assemble; Architecture
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Funding
- National Natural Science Foundation of China [21861012, 21603109]
- Henan Joint Fund of the National Natural Science Foundation of China [U1404216]
- Natural Science Foundation of Guizhou Education Commission [2018148, 2018016]
- Guizhou Science & Technology Commission [20201Z005, 20191157, 20191156]
- Natural Science Foundation of Shandong Province of China [ZR2016BM14]
- Tai'an Science & Technology Project [2016GX1046]
- Postgraduate Foundation of Taishan University [Y2015-1-011]
- Natural Science Foundation of Guizhou Minzu University [GZMU2019YB06]
- Natural Science Foundation of Liaoning Shihua University [2019XJJL019]
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A new copper-thiolate cluster assembled framework [Cu-2(mu(4)-SCH3)Cl](n) (1), has been solvothermally synthesized through in situ reaction viz., in situ ligand generation and metal reduction. Compound 1 represents the first 3D framework based on Atlas-sphere functionalized by single mu(2)-Cl groups. DOS calculation reveals the interaction of electronic structures. It is found that the HOMO is mainly distributed on Cl, Cu and S bonding orbitals, while the LUMO is dominated by Cu-Cl antibonding orbitals. (C) 2020 Chinese Chemical Society and Institute of Materia Medica, Chinese Academy of Medical Sciences. Published by Elsevier B.V. All rights reserved.
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