Journal
CHINESE CHEMICAL LETTERS
Volume 32, Issue 4, Pages 1367-1371Publisher
ELSEVIER SCIENCE INC
DOI: 10.1016/j.cclet.2020.09.060
Keywords
Thermally activated delayed fluorescence; Room temperature phosphorescence; White OLED; D-pi-A-pi-D architecture
Categories
Funding
- Program for National Natural Scientific Foundation of China [91833304, 61904120, 61775155, 61705158]
- Natural Science Foundation of Shanxi Province [201901D211090, 201903D121100, 201801D221124]
- Fundamental Research Funds for the Central Universities
- Shanxi Provincial Key Innovative Research Team in Science and Technology [201601D021043]
- Joint Research Funds of Department of Science & Technology of Shaanxi Province
- Northwestern Polytechnical University [2020GXLH-Z-006]
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A purely organic D-pi-A-pi-D type emitter with TADF and RTP properties was synthesized and showed efficient luminescence performance in solid state. Devices prepared by vacuum evaporation demonstrated near-white emission with high external quantum efficiency and long lifetime.
A purely organic D-pi-A-pi-D type emitter showing thermally activated delayed fluorescence (TADF) and room temperature phosphorescence (RTP) was designed and synthesized by utilizing the benzophenone as an acceptor and the N-phenyl-2-napthylamine as a donor moiety. It exhibits considerable TADF character in doped PMMA film and room temperature phosphorescence with a long lifetime of 74 ms at 466 nm in solid state. The devices with the configuration of ITO/Mo2O3 (4 nm)/mCP (30 nm)/mCP: x wt% NP2BP/TmTyPB (60 nm)/LiF (1.5 nm)/Al (100 nm) were prepared by vacuum evaporation to explore their electroluminescent performance. Interestingly, the non-doped device has obtained near-white emission with a fluorescence emission peak at 475 nm and a phosphorescence emission peak at 563 nm having the CIE coordinate of (0.23, 0.32) and the maximum external quantum efficiency of 1.09%. (C) 2020 Chinese Chemical Society and Institute of Materia Medica, Chinese Academy of Medical Sciences. Published by Elsevier B.V. All rights reserved.
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