4.7 Article

Ultalong nanowires self-assembled from a [b]-bisphenanthrene-fused azadipyrromethene

Journal

CHINESE CHEMICAL LETTERS
Volume 32, Issue 3, Pages 1249-1252

Publisher

ELSEVIER SCIENCE INC
DOI: 10.1016/j.cclet.2020.08.047

Keywords

AzaBODIPY; Self-assembly; H-aggregation; Nanowire; pi-Extended

Funding

  1. National Nature Science Foundation of China [21672006, 21672007, 21871006]
  2. Laboratorial Open Fund of Ministry of Education of Anhui Normal University [FMS201914]
  3. Natural Science Research Fund of BengBu Medical College [BYKY2019005ZD]

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1D microwires based on pi-extended azaBODIPY were successfully prepared and characterized, and an H-type aggregation was confirmed in the solution process. Characterization was done using SEM, XRD, and absorption spectroscopy. This research was published by Elsevier B.V., with all rights reserved.
The 1D microwires based on pi-extended azaBODIPY were successfully prepared and characterized for the first time. The bisphenanthrene-fused azaBPP-12C with four hydrophobic chains was prepared through de novo synthesis method involving the Suzuki reaction and subsequent oxidative ring-fused coupling. The microwires and aggregation behavior were studied using SEM, XRD and absorption spectroscopy. Finally, an H-type aggregation was confirmed in the solution process. (C) 2020 Chinese Chemical Society and Institute of Materia Medica, Chinese Academy of Medical Sciences. Published by Elsevier B.V. All rights reserved.

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