Journal
CHEMSUSCHEM
Volume 13, Issue 23, Pages 6056-6065Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cssc.202002246
Keywords
carbon dioxide; cycloaddition; homogeneous catalysis; organic carbonates; substrate assistance
Funding
- CERCA Program/Generalitat de Catalunya
- ICREA
- Spanish MINECO [CTQ2017-88920-P]
- AGAUR [2017-SGR-232]
- European Community [889754, 840557]
- Marie Curie Actions (MSCA) [840557, 889754] Funding Source: Marie Curie Actions (MSCA)
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The unparalleled potential of substrate-induced reactivity modes in the catalytic conversion of carbon dioxide and alcohol or amine functionalized epoxides is discussed in relation to more conventional epoxide/CO(2)coupling strategies. This conceptually new approach allows for a substantial extension of the substitution degree and functionality of cyclic carbonate/carbamate products, which are predominant products in the area of nonreductive CO(2)transformations. Apart from the creation of an advanced library of CO2-based heterocyclic products and intermediates, also the underlying mechanistic reasons for this novel reactivity profile are debated with a prominent role for the design and structure of the involved catalysts.
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