Journal
CHEMSUSCHEM
Volume 14, Issue 1, Pages 208-233Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cssc.202001865
Keywords
2D; 3D; COF; covalent organic framework; microwave-assisted synthesis
Funding
- Spanish Ministerio de Ciencia, Innovacion y Universidades [RTI2018-100910-B-C44, RTI2018-100910-B-C42, PEJ2018-004586-A]
- Generalitat Valenciana [CPTTGENT2018/004, APOTIP/2019/A/023]
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This article presents a comprehensive compilation of research results on microwave-assisted synthesis of COFs, covering the synthesis, characteristics, and general issues related to COFs and microwaves. Current and future perspectives on this topic are also discussed.
Covalent organic frameworks (COFs) are relatively recent materials. They have received great attention due to their interesting properties. However, the application of microwaves in their synthesis, despite its advantages such as faster and more reproducible processes, is a minority. Herein, a comprehensive compilation of the research results published in the microwave-assisted synthesis (MAS) of COFs is presented. This review includes articles of 2D and 3D COFs prepared using microwaves as source of energy. The articles have been classified depending on the functional groups including boronate ester, imines, enamines, azines, and triazines, among others. It compiles the main parameters of synthesis and characteristics of the materials together with some general issues related with COFs and microwaves. Additionally, current and future perspectives of the topic have been discussed.
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