Journal
CHEMOSPHERE
Volume 270, Issue -, Pages -Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.chemosphere.2020.128651
Keywords
Tetracycline degradation; Photocatalysis; Bi12O17Cl2/Ag/AgFeO2; Z-Scheme
Categories
Funding
- National Natural Science Foundation of China [51979101, 51739004, 51679082, 51521006]
- Hunan Science & Technology Innovation Program [2018RS3037]
- Natural Science Foundation of Hunan Province [2019JJ20002]
- Science and Technology Plan Project of Hunan Province [2018SK2047]
- Fundamental Research Funds for the Central Universities [531118010394]
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Tetracycline, a widely used antibiotic, poses risks to the aquatic ecosystem. A novel ternary Z-scheme Bi12O17Cl2/Ag/AgFeO2 exhibited enhanced photocatalytic degradation of tetracycline. Optimal catalyst concentration and pH conditions favored the degradation process, while exogenous anions and organic matter hindered it. O-center dot(2)- played a significant role in tetracycline degradation within the Bi12O17Cl2/Ag/AgFeO2 system.
Tetracycline (TC), a widely used antibiotic, is easy to enter the aquatic ecosystem through soil erosion, livestock manure and wastewater discharge, resulting in a series of risks. The application of Z-scheme photocatalysts with efficient interface charge separation and transfer has been regard as an effective strategy for antibiotic degradation. Herein, a novel ternary Z-scheme Bi12O17Cl2/Ag/AgFeO2 was successfully synthesized by ultrasound-assisted ethanol reduction of Ag+ on the interface of Bi12O17Cl2 and AgFeO2. The Bi12O17Cl2/Ag/AgFeO2 Z-scheme system exhibited an enhanced photocatalytic degradation capability for TC, which was over 6.5 times and 2.4 times higher than those of AgFeO2 and Bi12O17Cl2/AgFeO2 system, respectively. The photocatalytic process of TC was explored, and the results indicated that an optimum catalyst concentration of 0.5 g L-1 and a primeval pH (without adjustment) favored the degradation process, while the introduction of exogenous anions (CO32-, SO42- and NO3-) and organic matter (HA) supressed the degradation of TC. Simultaneously, the possible pathway for the degradation process of TC was presented based on the liquid chromatography-mass spectrometry (LC-MS) analysis. Active species trapping experiments and ESR spectra revealed the significant contribution of O-center dot(2)- in the TC degradation, and verified the Z-scheme mechanism of the Bi12O17Cl2/Ag/AgFeO2 system. (C) 2020 Elsevier Ltd. All rights reserved.
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