In-situ development of metal organic frameworks assisted ZnMgAl layered triple hydroxide 2D/2D hybrid as an efficient photocatalyst for organic dye degradation

Metal organic framework (MOF) supported layered triple hydroxide (LTH) 2D/2D hybrid material was prepared by a simple hydrothermal method. The photophysical properties of the prepared samples were investigated through a set of analytical methods such as X-ray diffraction, Fourier-transform infrared spectroscopy, field emission scanning electron microscope, high-resolution transmission electron microscopy, energy-dispersive X-ray spectroscopy and mapping. The photocatalytic degradation activity of as prepared 2D/2D MOF-5/LTH hybrid sample was investigated against methylene blue (MB) dye under the UVevisible light irradiation. The degradation efficiency of the MOF-5/LTH hybrid sample was twice a time greater than that of pristine MOF-5, particularly degradation efficiency of the MOF-5, LTH and MOF5/LTH hybrid samples are 43.3, 57.7 and 98.1% respectively. The Pseudo first order rate and the reusing investigation was further used to study the catalytic activity and stability of the as-synthesized 2D/2D photocatalyst. The observed improvement in the photocatalytic activity of the hybrid samples were owed to enhance visible light absorption, efficient separation and transportation of photoinduced electrons and holes. (C) 2020 Elsevier Ltd. All rights reserved.

Automated summary

A Metal organic framework (MOF) supported layered triple hydroxide (LTH) 2D/2D hybrid material was prepared using a simple hydrothermal method, and its photophysical properties were analyzed through various methods. The degradation efficiency of the MOF-5/LTH hybrid sample was found to be significantly higher, attributed to enhanced visible light absorption and efficient separation and transportation of photoinduced electrons and holes.