Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 26, Issue 67, Pages 15497-15500Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.202003521
Keywords
C− H activation; homogeneous catalysis; palladium; synthetic methodology; thiocyanation
Categories
Funding
- Normandie Universite (NU)
- Region Normandie
- Centre National de la Recherche Scientifique (CNRS)
- Labex SynOrg [ANR-11-LABX-0029]
- Innovation Chimie Carnot (I2C)
- European Research Council (ERC) under the European Union [758710]
- French National Research Agency [ANR-17-CE07-0038-01]
- Region Normandy
- Universitede Rouen Normandie (URN)
- INSA Rouen Normandie
- Agence Nationale de la Recherche (ANR) [ANR-17-CE07-0038] Funding Source: Agence Nationale de la Recherche (ANR)
- European Research Council (ERC) [758710] Funding Source: European Research Council (ERC)
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The Pd-catalyzed directed thiocyanation reaction of arenes and heteroarenes by C-H bond activation was achieved. In the presence of an electrophilic SCN source, this original methodology offered an efficient tool to access a panel of functionalized thiocyanated compounds (21 examples, up to 78 % yield). Post-functionalization reactions further demonstrated the synthetic utility of the approach by converting the SCN-containing molecules into value-added scaffolds.
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