4.6 Article

Synthesis and Optoelectronic Properties of a Quinoxalino-Phenanthrophenazine (QPP) Extended Tribenzotriquinacene (TBTQ)

Journal

CHEMISTRY-A EUROPEAN JOURNAL
Volume 27, Issue 6, Pages 2043-2049

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.202003666

Keywords

electronic communication; heterocycles; pyrenes; quinoxalinophenanthrophenazine; tribenzotriquinacene

Funding

  1. Deutsche Forschungsgemeinschaft [SFB1249]
  2. Projekt DEAL

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The six-step synthesis of TBTQ bearing three QPP units was presented and its optoelectronic properties were investigated through optical spectroscopy, electrochemical analysis, and quantum-chemical calculations. The effect of the three-dimensional arrangement of the individual QPP planes was examined.
A six-step synthesis towards a tribenzotriquinacene (TBTQ) bearing three quinoxalinophenanthrophenazine (QPP) units is presented. The optoelectronic properties are investigated and the effect of the three-dimensional arrangement of the individual QPP planes is examined using optical spectroscopy, electrochemical analysis and quantum-chemical calculations.

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