Journal
CHEMICAL PHYSICS LETTERS
Volume 754, Issue -, Pages -Publisher
ELSEVIER
DOI: 10.1016/j.cplett.2020.137681
Keywords
Iron cyanides; Photochemistry; Soft X-ray absorption
Funding
- ERC-ADG-2014 under the Horizon 2020 EU Framework Program for Research and Innovation [669531 EDAX]
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It is demonstrated for the case of photo-excited ferrocyanide how time-resolved soft X-ray absorption spectroscopy in transmission geometry at the ligand K-edge and metal L-3-edge provides quantitatively equivalent valence electronic structure information, where signatures of photo-oxidation are assessed locally at the metal as well as the ligand. This allows for a direct and independent quantification of the number of photo-oxidized molecules at two soft X-ray absorption edges highlighting the sensitivity of X-ray absorption spectroscopy to the valence orbital occupation of 3d transition metal complexes throughout the soft X-ray range.
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