4.7 Article

Hierarchical design of waterproof, highly sensitive, and wearable sensing electronics based on MXene-reinforced durable cotton fabrics

Journal

CHEMICAL ENGINEERING JOURNAL
Volume 408, Issue -, Pages -

Publisher

ELSEVIER SCIENCE SA
DOI: 10.1016/j.cej.2020.127363

Keywords

MXene; Multi-mode sensors; Superhydrophobic; Highly sensitive; Antifouling

Funding

  1. National Natural Science Foundation of China [51773129, 51903167]
  2. Support Plan of Science and Technology Department of Sichuan Province, China [2019YFG0257, 2020YFG0071]
  3. International Science and Technology Cooperation Program of Chengdu [2019-GH02-00021-HZ]
  4. Miaozi Project in Science and Technology Innovation Program of Sichuan Province [2020061]

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A waterproof, highly sensitive, and wearable multi mode sensor was successfully fabricated by constructing 2D MXene nanosheets and zero-dimension silicon nanoparticles onto a cotton fibers substrate. The sensor showed superior performance in sensing pression, bending, and torsion, with stable response and broad sensing ranges.
Superhydrophobic wearable textile electronics are of great promising devices due to their broad application in healthcare monitoring and artificial intelligence, etc. MXenes, the emerging two-dimensional (2D) carbides and carbonitrides, are ideal candidates for fabricating wearable electronic devices. However, in an effort to maintain its highly conductive and long-term stability of cotton fabrics under harsh condition, it is an imperative demand to prepare superhydrophobic MXenes-textile sensor. Herein, a waterproof, highly sensitive, and wearable multi mode sensor was successfully fabricated by the construction of 2D MXene nanosheets and zero-dimension (0D) silicon nanoparticles (SiNPs) onto a cotton fibers substrate (MX@SiNPs cotton). The as-cultivated MX@SiNPs cotton exhibited an integration of high-performance sensing toward pression, bending, and torsion, superior sensitivity (S-1 = 12.23 kPa(-1)), a stable response under press-relaxing cycles, and broad sensing ranges (pressure: 8.8 Pa - 70 kPa, bending: 0 - 180 degrees, torsion: 0 - 628 rad m(-1)). By virtue of its hierarchical structure and low surface energy of the SiNPs layer, the MXenes-textile sensor can maintain intrinsic conductivity under wet and corrosive conditions. The waterproof and highly sensitive MXene-reinforced cotton fabrics lay a basis for the broad-range application and large-scale preparation of the sensor and prolong its service life.

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