Highly flame-retardant epoxy-based thermal conductive composites with functionalized boron nitride nanosheets exfoliated by one-step ball milling

Boron nitride nanosheet (BNNS) reveals a huge potential in preparing highly flame-retardant polymer-based thermal conductive composite, but is limited by its difficult exfoliation and functionalization. Here, hexagonal boron nitride (hBN) was simultaneously exfoliated and flame-retardant functionalized into BNNS via one-step ball milling process based on the synergetic effect of mechanical shear and chemical peeling of ammonium phosphate and sodium hydroxide. Then the epoxy (EP)-based composites containing hBN or BNNS were prepared by solution blending and program-controlled curing. The possible mechanochemical reaction mechanisms were proposed according to the incorporation of density functional theory (DFT) calculations and chemical structure characteristics. As one of potential applications, the obtained flame-retardant functionalized BNNS (BNNS1 and BNNS2) were used as multifunctional additives for fabricating high-performance EP-based thermal conductive composites with excellent flame retardancy. As expected, the obtained EP-based composites containing only 5 wt % BNNS exhibited a superior flame retardancy with a dramatic decrease in the values of peak heat release rate (PHRR), the total heat release (THR), the smoke production rate (SPR) and the total smoke production (TSP) corresponding to 60.9%, 35.7%, 44.3% and 38.8% reductions, respectively, compared to neat EP. The dramatical enhancement in flame retardancy was mainly attributed to the catalytic charring effect and physical barrier action of flame-retardant functionalized BNNS, led to the formation of a compact and robust char layer during combustion to protect the underlying polymer. Simultaneously, due to uniform dispersion and strong interfacial adhesion, the incorporation of BNNS not only increased the thermal conduction paths by increasing specific surface area, but also reduced the interfacial thermal resistance (R-b) caused by phonon scattering, leading to an enhancement (312.4% and 397.0%) in the TC of EP/BNNS composites at 30 wt% BNNSi and BNNS2, respectively.

Automated summary

In this study, hexagonal boron nitride was exfoliated and flame-retardant functionalized in one step via ball milling, leading to the development of highly flame-retardant and thermally conductive composite materials. The obtained BNNS were used as multifunctional additives in epoxy resin composites, showing significant improvements in flame retardancy and thermal conductivity.