Journal
CHEMICAL ENGINEERING JOURNAL
Volume 396, Issue -, Pages -Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.cej.2020.125196
Keywords
Self-healing coating; Cellulose; Halloysite nanotubes; Epoxy; Coatings
Categories
Funding
- Iran National Science Foundation (INSF) [97022039]
- INSF
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Self-healing and self-repairing coatings are stimuli-responsive materials, which are of crucial importance in developing advanced smart systems. However, a few has been attempted to unveil the association between the microstructure and properties of self-healing organic coatings. Herein, silane coupled cellulose-functionalized halloysite nanotubes (HNT-C)/epoxy nanocomposite coatings showing vitrimer-like behavior were developed and their crosslinking, thermal, mechanical, and self-healing behaviors were discussed. Nanocomposites with variable pristine HNT and HNT-C contents (0.1, 0.3, and 0.5 wt%) were prepared, where epoxy/HNT-C (0.3 wt %) took Good cure label in terms of Cure Index, surprisingly with a cure enthalpy three times higher than that of blank epoxy. Moreover, the tensile strength and elongation at break of the assigned nanocomposite coating were enhanced by 16% and 56%, respectively. Evidence of cellulose functionalization was in SEM image provided from the fracture surface suggesting smooth breakup mechanism for epoxy and epoxy/HNT, in contrast to a roughly-broken fracture behavior for epoxy/HNT-C. Surface functionalization of nanotubes with cellulose decreased the relaxation time by five times in some cases, which was ascribed to the esterification reaction in the system. The self-healing behavior of the coatings through transesterification of beta-hydroxyl ester at higher temperature was theoretically interpreted in terms of relaxation time of the epoxy chains. The vitrimers rapidly responded to the intra/inter molecular forces because of the transesterification reaction so that the ester groups were exchanged with hydroxyl groups that assisted autocatalytic reactions. The epoxy/HNT-C nanocomposites developed in this work are fast cure coatings with acceptable toughness and self-healing behavior.
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