4.7 Article

Rutile-perovskite multi-phase composite by mechano-chemical method together with calcination: Preparation and application in coatings and ceramic glaze

Journal

CERAMICS INTERNATIONAL
Volume 47, Issue 2, Pages 2261-2269

Publisher

ELSEVIER SCI LTD
DOI: 10.1016/j.ceramint.2020.09.066

Keywords

Metatitanic acid; Rutile-perovskite multi-phase composite; Mechano-chemical method; Pigment properties; Coatings; Ceramic glaze

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In this article, rutile-perovskite multi-phase composite was synthesized by mechano-chemical method and calcination, with optimized parameters and excellent pigment properties demonstrated. The composite shows great potential in applications such as coatings and ceramic glaze, showcasing its extensive industrial usability.
In this article, rutile-perovskite multi-phase composite was produced using mechano-chemical method followed by calcination with metatitanic acid and GCC as raw materials. The relative parameters in mechano-chemical method, such as slurry concentration, grinding time and ball to powder ratio, and the relative parameters in calcination, namely calcination temperature and calcination time, were researched systematically in order to get the optimum value. The structure and morphology of the final product were characterized and the reaction mechanism was investigated. The final product, namely the rutile-perovskite multi-phase composite, has excellent pigment properties comparable to titanium white. It also has excellent performances in coatings and ceramic glaze. All of these prove that the produced rutile-perovskite multi-phase composite can be used extensively in industry due to its excellent pigment properties together with simple reaction conditions.

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