4.7 Article

Estimating the density and molar volume of ferrite-based ternary molten slags by geometrical model

Journal

CERAMICS INTERNATIONAL
Volume 47, Issue 1, Pages 634-642

Publisher

ELSEVIER SCI LTD
DOI: 10.1016/j.ceramint.2020.08.171

Keywords

Ferrite-based slags; Density; Molar volume; Geometrical model; Estimation

Funding

  1. National Natural Science Foundation of China [51734002]
  2. China Postdoctoral Science Foundation [2020M671071]

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Research has shown that using a geometrical model can effectively estimate the density and molar volume of ferrite-based ternary slags, providing important data for optimizing the metallurgical process.
Ferrite-based slags are the basic systems in the pyrometallurgical production of copper, and the density and molar volume of these systems are of vital importance for optimizing the metallurgical process. However, due to the high melting points of melts and the expensive trial costs, experimental methods are inefficient to obtain all the data needed. As a result, a geometrical model has been applied to the estimation of density and molar volume of ferrite-based ternary slags. The calculated results agree well with experimental data in three ferrite-based ternary systems of Fe2O3-CaO-FeO, Fe2O3-BaO-FeO and Fe2O3-CaO-Cu2O. The mean deviation of the pre-dicted results by the present model is lower than those by various empirical models for corresponding systems. The application of the present will enrich the data of density and molar volume for more ternary melts.

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