4.7 Article

Cavitation erosion characteristics at various flow velocities in NaCl medium of carbide-based cermet coatings prepared by HVOF spraying

Journal

CERAMICS INTERNATIONAL
Volume 47, Issue 2, Pages 1929-1939

Publisher

ELSEVIER SCI LTD
DOI: 10.1016/j.ceramint.2020.09.022

Keywords

Cavitation erosion; HVOF; Flow velocity; Cermet; Coating

Funding

  1. National Natural Science Foundation of China [51979083, 51609067, 51975183]
  2. China Postdoctoral Science Foundation [2018T110435, 2017M621665]
  3. Postdoctoral Science Foundation of Jiangsu Province [2018K022A]
  4. Shuangchuang Program of Jiangsu Province

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The study found that WCN coating exhibited higher hardness and elastic modulus, lower volume loss rate, and enhanced CE resistance compared to CN coating in NaCl medium. Increasing flow velocity led to higher volume loss rates for both coatings.
This study aims to investigate the correlation between flow velocity and cavitation erosion (CE) characteristics of high-velocity oxygen-fuel (HVOF) sprayed Cr3C2-NiCr (CN) and WC-Cr3C2-Ni (WCN) coatings in 3.5 wt% NaCl medium, except for the microstructures, mechanical properties and electrochemical behaviors. In comparison with the CN coating, the WCN coating shows higher values of elastic modulus (E), hardness (H), H/E and H-3/E-2 as well as lower porosity, resulting in lower volume loss rate (VLR) and enhanced CE resistance in NaCl medium at each value of flow velocity. The VLR values of both coatings increase as the flow velocity increases. The change of the CE progresses in NaCl medium of the CN coating is the formation of cavitation pinholes, pits, craters and oxidation films coupled with the exfoliation of chromium carbide particles when the flow velocity is 23.4 and 33.5 m s(-1) as well as the brittle fracture structure with layers delamination accompanied by the oxidation films when the flow velocity is 41.9 m s(-1). In a wide flow velocity range, the formation of cavitation pinholes, pits and micro-cracks along with the oxidation films are addressed as the dominant CE mechanism in NaCl medium of the WCN coating.

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