Production of liquid fuel intermediates from furfural via aldol condensation over La2O2CO3-ZnO-Al2O3 catalyst

Aldol condensation of furfural with acetone over basic catalysts allows the production of furanic adducts 4-(2-furyl)-3-buten-2-one (FAc, C8) and 1,5-di-2- furanyl-1,4-pentadien-3-one (F2Ac, C13)) that can be transformed into high-quality diesel fuels by further hydrogenation. However, the development of efficient basic catalysts and understanding of role of basic sites with different strength are still required. In this work, monoclinic and hexagonal La2O2CO3 promoted ZnO-Al2O3 catalysts were synthesized with higher concentration of medium strength basic sites and better catalytic performance as compared with La2O3 and ZnO-Al2O3. This work demonstrated that the medium strength basic sites were especially active for aldol condensation reactions.

Automated summary

Aldol condensation of furfural with acetone over basic catalysts produces furanic adducts that can be transformed into diesel fuels. This study synthesized La2O2CO3-promoted ZnO-Al2O3 catalysts with medium strength basic sites, showing improved catalytic performance. The medium strength basic sites were found to be especially active for aldol condensation reactions.