4.8 Article

Multi-shell hollow porous carbon nanoparticles with excellent microwave absorption properties

Journal

CARBON
Volume 172, Issue -, Pages 542-555

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.carbon.2020.10.062

Keywords

Hollow; Porous; Multi-shell; Layer-by-Layer; Microwave absorption

Funding

  1. National Natural Science Foundation of China [51672129, 52002337]
  2. Open Fund of Key Laboratory of Materials Preparation and Protection for Harsh Environment (Nanjing University of Aeronautics and Astronautics), Ministry of Industry and Information Technology [56XCA19013-05]

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The study focused on the micro-morphology design of nanomaterials for improved microwave absorption properties. Results showed that the multi-shell structure enhanced the microwave absorption performance of carbon nanoparticles, with the three-shell structure achieving an effective absorption bandwidth of 5.17 GHz at a thickness of 1.6 mm and a best reflection loss of -18.13 dB.
The micro-morphology design of nanomaterials has always been a hot issue in the field of microwave absorption. In this work, multi-shell structure is made on the basis of hollow structure and porous structure, and the effect of shell number of nanoparticles on microwave absorption properties is studied. Multi-shell hollow porous carbon nanoparticles (HPCNs-m) were prepared by simple liquid phase method combined with layer-by-layer process, and their micro-morphology, chemical structure, electromagnetic properties and microwave absorption properties were studied by a variety of characterization methods. The results show that the multi-shell structure is beneficial to improve the conductivity loss and polarization loss, so as to enhance the microwave absorption properties of the samples. In all samples, the effective absorption bandwidth (EAB) of three-shell hollow porous carbon nanoparticles (HPCNs-3) is 5.17 GHz under the thickness of 1.6 mm, and the best reflection loss (RL) is -18.13 dB at 14.66 GHz. This work expands the study of the effect of the number of shells on microwave absorption properties, and provides a useful reference for the design of microwave absorbers. (C) 2020 Elsevier Ltd. All rights reserved.

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