Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 60, Issue 6, Pages 2855-2860Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.202011740
Keywords
circularly polarized luminescence; kinetic traps; self-assembly; vibration-induced emission; visual monitoring
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Funding
- National Natural Science Foundation of China [21788102, 22020102006, 21722603, 21871083]
- Shanghai Municipal Science and Technology Major Project [2018SHZDZX03]
- Program of Shanghai Academic/Technology Research Leaders [20XD1421300]
- Shanghai Municipal Education Commission
- Shanghai Education Development Foundation [19SG26]
- Innovation Program of Shanghai Municipal Education Commission [2017 01-07-00-02-E00010]
- Fundamental Research Funds for the Central Universities
- Shu Guang project
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This study monitored the self-assembly process of chiral DPAC derivatives in real time using vibration-induced emission, revealing distinct optical and morphological characteristics of different assemblies. Additionally, strong circularly polarized luminescence was induced during the morphology transformation process. The excited-state characteristics of the self-assemblies allowed effective investigation of the relationship between molecular aggregation and conformational change.
The construction of artificial structures through hierarchical self-assembly based on noncovalent interactions, as well as monitoring during the self-assembly process, are important aspects of dynamic supramolecular chemistry. Herein we describe the complex dynamics of chiral N,N '-diphenyl dihydrodibenzo[a,c]phenazine derivatives (S)/(R)-DPAC, whose different assemblies were found to have distinct optical and morphological characteristics. With ratiometric fluorescence originating from vibration-induced emission (VIE), the self-assembly process from kinetic traps to the thermodynamic equilibrium state could be monitored in real time by optical spectrometry. During the morphology transformation from particles to nanobricks, strong circularly polarized luminescence was induced with g(lum)=1.6x10(-2). The excited-state characteristics of the self-assemblies enabled investigation of the relationship between molecular aggregation and conformational change, thus allowing effective monitoring of the sophisticated supramolecular self-assembly process.
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