Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 362, Issue 21, Pages 4716-4722Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.202000818
Keywords
O-H functionalization; cyclic diazoamides; photochemistry; fluorine
Categories
Funding
- German Science Foundation
- Dean's Seed Fund of RWTH Aachen Foundation
- RWTH Aachen University
- Projekt DEAL
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Herein, we describe the photochemical O-H functionalization reaction of acidic alcohols with cyclic diazoamides. We studied the O-H functionalization reaction of different fluorinated and non-fluorinated alcohols to give the corresponding ether products in high yields (43 examples, up to 97% yield). Furthermore, we performed studies to evaluate a photoexcited proton transfer reaction pathway in comparison to classic carbene transfer reactions.
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