Journal
ADVANCED FUNCTIONAL MATERIALS
Volume 31, Issue 4, Pages -Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adfm.202007276
Keywords
gravure printing; large-area flexible electrodes; polymer solar cells; silver nanowires; surface morphology
Categories
Funding
- National Natural Science Foundation of China [51773224]
- Chinese Academy of Sciences [2019317, GJHZ2092-019]
- Suzhou Institute of Nano-Tech and Nano-Bionics Nanchang [2017CA01, 2019DH17]
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This study reports a method for developing high-performance flexible polymer solar cells using a high-throughput gravure printing process. By adjusting the blend ratio of the mixture solvent and the concentration of silver nanowire inks, the properties of the ink can be tuned to achieve uniformly printed films that meet the requirements of the printing process. The resulting flexible transparent electrodes exhibit high conductivity and transparency, comparable to traditional indium tin oxide electrodes.
With the aim of developing high-performance flexible polymer solar cells, the preparation of flexible transparent electrodes (FTEs) via a high-throughput gravure printing process is reported. By varying the blend ratio of the mixture solvent and the concentration of the silver nanowire (AgNW) inks, the surface tension, volatilization rate, and viscosity of the AgNW ink can be tuned to meet the requirements of gravure printing process. Following this method, uniformly printed AgNW films are prepared. Highly conductive FTEs with a sheet resistance of 10.8 omega sq(-1)and a high transparency of 95.4% (excluded substrate) are achieved, which are comparable to those of indium tin oxide electrode. In comparison with the spin-coating process, the gravure printing process exhibits advantages of the ease of large-area fabrication and improved uniformity, which are attributed to better ink droplet distribution over the substrate. 0.04 cm(2)polymer solar cells based on gravure-printed AgNW electrodes with PM6:Y6 as the photoactive layer show the highest power conversion efficiency (PCE) of 15.28% with an average PCE of 14.75 +/- 0.35%. Owing to the good uniformity of the gravure-printed AgNW electrode, the highest PCE of 13.61% is achieved for 1 cm(2)polymer solar cells based on the gravure-printed FTEs.
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