Journal
NPJ QUANTUM MATERIALS
Volume 5, Issue 1, Pages -Publisher
NATURE PORTFOLIO
DOI: 10.1038/s41535-020-00259-5
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Funding
- U.S. Department of Energy, Office of Basic Energy Sciences, Materials Science Division [DE-FG02-01ER45885]
- National Science Foundation DMREF Grant [DMR-1629059]
- Gordon and Betty Moore Foundation's EPiQS Initiative [GBMF9069]
- Department of Energy [DE-AC98-06CH10886]
- COMPRES under NSF [EAR 11-57758]
- CDAC [DE-FC03-03N00144]
- Basic Science Research Program through the National Research Foundation of Korea - Ministry of Education [NRF-2019R1G1A1100614]
- National Supercomputing Center of Korea [KSC-2019-CRE-0036]
- Center for Materials Processing, a Tennessee Higher Education Commission (THEC)
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van der Waals materials are exceptionally responsive to external stimuli. Pressure-induced layer sliding, metallicity, and superconductivity are fascinating examples. Inspired by opportunities in this area, we combined high-pressure optical spectroscopies and first-principles calculations to reveal piezochromism in MnPS3. Dramatic color changes (green -> yellow -> red -> black) take place as the charge gap shifts across the visible regime and into the near infrared, moving systematically toward closure at a rate of approximately -50 meV/GPa. This effect is quenched by the appearance of the insulator-metal transition. In addition to uncovering an intriguing and tunable functionality that is likely to appear in other complex chalcogenides, the discovery that piezochromism can be deterministically controlled at room temperature accelerates the development of technologies that take advantage of stress-activated modification of electronic structure.
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